2-Chloro-N-(4-methoxybenzoyl)benzenesulfonamide
نویسندگان
چکیده
In the title compound, C14H12ClNO4S, the dihedral angle between the aromatic rings is 82.07 (1)° and the dihedral angle between the planes defined by the S-N-C=O fragment and the sulfonyl benzene ring is 82.46 (3)°. In the crystal, the mol-ecules are linked into C(4) chains running along [001] by strong N-H⋯O hydrogen bonds. A C-H⋯O intera-ction reinforces the [001] chains: its graph-set symbol is C(7). The chains are cross-linked into (100) sheets by further C-H⋯O inter-actions as C(6) chains along [001]. The structure also features weak π-π stacking inter-actions [centroid-centroid distances = 3.577 (1) and 3.8016 (1) Å].
منابع مشابه
2-Chloro-N-(3-methoxybenzoyl)benzenesulfonamide
In the title compound, C14H12ClNO4S, the dihedral angle between the chloro- and meth-oxy-substituted benzene rings is 87.40 (1)°. In the crystal, adjacent mol-ecules form inversion-related dimers through strong N-H⋯O hydrogen bonds, generating R 2 (2)(8) loops. The dimers are further connected through two C-H⋯O inter-actions that form C(11) chains and R 2 (2)(14) loops. Aromatic π-π stacking in...
متن کامل4-Chloro-N-(3-chlorophenyl)benzenesulfonamide
In the crystal of the title compound, C(12)H(9)Cl(2)NO(2)S, the mol-ecule is twisted at the S atom with a C-SO(2)-NH-C torsion angle of -58.4 (3)°. Furthermore, the N-H bond in this segment is anti to the meta-chloro group. The dihedral angle between the aromatic rings is 77.1 (1)°. The crystal structure features inversion-related dimers linked by N-H⋯O hydrogen bonds.
متن کامل4-Chloro-N-(3,5-dichlorophenyl)benzenesulfonamide
In the title compound, C(12)H(8)Cl(3)NO(2)S, the dihedral angle between the aromatic rings is 87.9 (1)° and the C-S-N-C torsion angle is 77.8 (2)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.
متن کامل4-Chloro-2-methyl-N-(2-methylphenyl)benzenesulfonamide
In the crystal structure of the title compound, C(14)H(14)ClNO(2)S, the two aromatic rings are tilted relative to each other by 45.8 (1)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.
متن کامل2-Chloro-N-(4-chlorobenzoyl)benzenesulfonamide toluene hemisolvate
The unit cell of the title compound, C(13)H(9)Cl(2)NO(3)S·0.5C(7)H(8), contains two mol-ecules of 2-chloro-N-(4-chloro-benzo-yl)benzene-sulfonamide and one toluene mol-ecule, which is disordered about a centre of inversion. The dihedral angle between the two aromatic rings is 85.7 (1)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming centrosymmetric dimers.
متن کامل